Description
10 sections • 190 lectures • 23h 56m total lengthSection 1: Basic Concepts of Organic Chemistry (33 video lectures): 1. Chemical Bonds2. Common Bonding Pattern3. Lewis Structure4. Lewis Structure-Sample problems5. Resonance forms6. Resonance Hybrid7. Formal Charge8. Exception to the Octet Rule9. Resonance Contribution10. Functional Groups11. Molecular Geometry12. Condensed Structure of Organic Molecules13. Line-angle or Skeletal Structure of Organic Molecules14. Skeletal Structures with Charged Carbons-Carbocations and Carbanions15. Structural or Constitutional Isomers16. Atomic and Hybrid Orbitals17. Determining Hybridization18. Sigma and pi Bonds in Double and Triple Bonds19. Electronegativity and Polarity of Bonds and Molecules20. Factors affecting Bond length and Bond energy21. Intermolecular Interactions22. Intermolecular Forces and Boiling and Melting Points23. Solubility of Organic Molecules-Like dissolves Like24. Hydrophobic and Hydrophilic parts25. Acids and Bases26. The extent of Reaction between Acids and Bases27. Factors affecting Acidity28. Lewis Acids-Lewis Bases29. Electrophiles and Nucleophile30. Energy Diagrams31. Energy Diagrams of Two-Step Reactions32. Rate Equations33. CatalystsSection 2: Alkanes (19 video lectures)1. Introduction to Alkanes and Cycloalkanes2. Naming Branched Alkanes3. Naming Cycloalkanes4. Classification of Carbon and Hydrogen Atoms5. Constitutional or Structural Isomers6. Cis-Trans Isomerism in cycloalkanes7. Conformations of Alkanes8. Neman Projection9. Conformational Analysis of Ethane10. Conformational Analysis of Propane11. Newman projections of Butane12. Conformational Analysis of Butane13. Angle Strain and Torsional Strain in Cycloalkanes14. Conformational Analysis of Cyclohexane15. 1,3-Diaxila Interaction in Cyclohexane Derivatives16. Conformational change of methyl cyclohexane-Newman projection17. Conformations of disubstituted cyclohexane18. Sample problems of Conformations of disubstituted cyclohexane19. Polycyclic CompoundsSection 3: Stereochemistry (18 video lectures)1. Stereoisomers2. Enantiomers-Chiral Molecules3. R and S configuration assignment4. Determination of priorities for double and triple bonds5. Fischer projection6. Sample problems for configuration assignment7. Diastereomers8. Meso compounds9. Stereochemistry of conformations of Butane10. Conformational enantiomers11. Sample problems for relationship between stereoisomers-112. Sample problems for relationship between stereoisomers-213. Plane-polarized Light and distinguishing Enantiomers14. Specific rotation15. Racemic mixtures16. Physical properties of stereoisomers17. Enantiomeric excess or optical purity18. Conversion of achiral reactant to chiral productSection 4: Substitution (25 video lectures)1. Introduction to Substitution Reactions2. Alkyl-Vinyl-Aryl-Benzyl Halides3. Naming Alkyl Halides4. Nucleophilicity versus Basicity5. SN2 Mechanism-Introduction6. Energy Diagram of SN2 Reactions7. Inversion of configuration in SN2 reactions8. Effect of Nucleophile on SN2 Reactions9. Effect of Solvent on SN2 Reactions10. Effect of Leaving group on SN2 Reactions11. Effects of Substrate on SN2 Reactions12. SN1 Mechanism-Introduction13. Energy Diagram of SN1 Reactions14. Effects of Substrate on SN1 Reactions15. Effect of Solvent on SN1 Reactions16. Stereochemistry of SN1-Racemization17. SN1 Reaction on a Ring18. Rearrangements in SN1 Reaction19. Effect of Nucleophile on SN1 Reactions20. Effect of Nucleophile on Substitution Reaction of Secondary Alkyl Halides21. Effect of Leaving Group on SN1 Reactions22. Aryl and Vinyl Halides-SN1 and SN2 Reactions23. Sample Problems of SN1 Reactions24. Sample problems of SN1 and SN2 Reactions25. Characteristics of SN2 and SN1 ReactionsSection 5: Elimination (23 video lectures)1. Introduction to Elimination Reaction2. Structures and Stereoisomers of Alkenes3. Classification and and relative energy of Alkenes4. E1 Mechanism-Introduction5. Energy Diagram for E1 Reactions6. Effect of Alkyl Halide Structure on E1 Reactions7. Zaitsev Rule8. Regioselectivity of E1 Reactions9. Rearrangements in E1 Mechanism10. Effect of Leaving Group on E1 Reactions11. Effect of Solvent on E1 Reactions12. Competition Between the SN1 and E1 Reactions13. E2 Mechanism-Introduction14. Energy Diagram for E2 Reactions15. Effect of Alkyl Halide Structure on E2 Reactions16. Regioselectivity and Stereoselectivity of E2 Reactions17. Effect of Leaving Group on E2 Reactions18. Effect of Solvent on E2 Reactions19. Elimination Reactions under E1 or E2 conditions20. Stereospecifity of E2 Reactions21. Comparison of E2 and E1 Mechanisms22. Anti-coplanar Orientation for E2 Reactions23. E2 Reactions on Halocyclohexanes-Zaitsev and anti-Zaitsev productsSection 6: Alkenes (24 video lectures)6. Structure of Alkenes2. Degrees of Unsaturation3. Alkene Nomenclature4. Cis-Trans and E-Z Geometric Isomers5. Hydrogenation of Alkenes6. Dehydrohalogenation by E27. Zaitsev and Hofmann Products8. Dehydrohalogenation by E19. Dehalogenation of Vicinal Dibromides10. Reactions of Alkenes11. Hydrohalogenation of Alkenes12. Markovnikov's Rule13. Hydration of Alkenes14. Oxymercuration-Demercuration15. Hydroboration-Oxidation16. Halogenation of Alkenes17. Halohydrin Formation18. Cyclopropanation Reaction19. Epoxidation Reaction20. Syn Dihydroxylation of Alkenes21. Anti Dihydroxylation of Alkenes22. Oxidative cleavage of Alkenes23. Ozonolysis of Alkenes24. Polymerization of AlkenesSection 7: Alkynes (10 video lectures)1. Alkynes nomenclature and structure2. Alkyne Synthesis using Dehydrohalogenation3. Formation of Acetylide Ions4. Reactions of Acetylide Ions5. Hydrogenation of Alkynes6. Halogenation of Alkyne7. Hydrohalogenation of Alkyne8. Hydration of Alkynes9. Hydroboration of Alkynes10. Oxidative cleavage of AlkynesSection 8: Alcohols (17 video lectures)1. Structure of Alcohols2. Acidity of Alcohols3. Organometallic Reagents4. Preparation of Alcohols using R-Li5. Preparation of Alcohols using Grignard Reagent6. Preparation of Alcohols using Hydride Reduction7. Introduction to Reactions of Alcohols8. Oxidation of Alcohols9. Tosylation of Alcohols for SN2 and E2 Reactions10. Conversion of Alcohols to Alkyl Halides with HX11. Reaction of Alcohols with Lucas Reagent12. Conversion of 1 and 2 Alcohols into R-Br using PBr313. Conversion of 1 and 2 Alcohols into R-Cl using SOCl214. Dehydration of Alcohols15. Dehydration of Alcohols and Carbocation Rearrangements16. Dehydration of Alcohols using POCl317. Pinacol RearrangementSection 9: Ethers-Epoxides-Sulfides (13 video lectures)1. Structures and Nomenclatures of Ethers-Epoxides-Sulfides2. Williamson Ether Synthesis3. Synthesis of Ethers using Bimolecular Dehydration of Alcohols4. Electrophilic Addition of Alcohols to Alkenes5. Alokoxymercuraion-Demercuration Reaction6. Reaction of an Ether with Hydrohalic Acids7. Epoxidation of Alkenes8. Forming Epoxides from Halohydrins9. Acid-Catalyzed Opening of Epoxides10. Base-Catalyzed Opening of Epoxides11. Organometallic Reactions with Epoxides12. Reactions of Epoxides with Lithium Aluminum Hydride13. Sulfides (Thioether)Section 10: Radical Reactions (8 video lectures)1. Structure of Radicals2. Radical Halogenation of Alkanes3. Energy Diagram for Radical Propagation4. Product Mixture in Radical Halogenation5. Allylic Halogenation using NBS6. Regiochemistry of Allylic Halogenation7. Radical Addition of H-Br to Alkenes8. Sample Problems of Radical Substitution Reaction
